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ArifOS is the first AI governance kernel that ensures constitutional-level safety, ethical, and truth constraints on any language model output. It transforms arbitrary AI models into auditable, compliant, and safe systems by enforcing thermodynamic governance floors that actively prevent hallucination, harm, and unverified assertions. Unlike traditional training-time approaches or prompt-based guardrails, ArifOS embeds governance at the architectural level, providing robust runtime enforcement, physics-based governance, and immutable audit trails through its thermodynamic constraint engine and cryptographic sealing.